REFERENCEPAGES 1-800-833-7958 www.geotechenv.com fax303-322-7242 sales@geotechenv.com ChemicalCompatibilityTable For All Non-Metals For Metals R=Resistant E<2milsPenetration/Year startxref
165 0 obj Oxidative and other lubricant degradation mechanisms would follow the same trend. Satisfactory to 72 F. 3. June 16, 2022; Posted by usa volleyball national qualifiers 2022; 16 . Oils made with PAOs demonstrate an inherently high viscosity index and maintain excellent low-temperature performance, compared with mineral oils. These synthetic hydrocarbons are designed to provide superior lubrication performance over a wider operating-temperature range than petroleum oils and typically are less volatile. PAG-based lubricants have excellent viscosity indices significantly better than PAO-based lubricants of the same viscosity grade. When unsure of a components precise identity or version, the manufacturer This is a recurring situation and is what led to the development of 1-dodecene based Synfluid PAOs in 1995. Although PAOs are not considered biobased themselves, in a blend they contribute certain performance benefits. When PAO 5 and PAO 7 are compared to equiviscous blends of other PAOs, the volatility advantage can be seen more clearly. Give us a call. Our safety, technical and regulatory product information, as well as company and industry resources. This article will discuss the most common synthetic fluids aiming to help end-users make the right choice for their applications. application/pdf The lower volatility of Synfluid PAOs 5, 7 and 9 enhances the benefits for the highest quality lubricant. Synfluid PAOs are already known for their excellent low-temperature and oxidative stability properties. 0000000416 00000 n
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The Scanning Brookfield chart on this page demonstrates the difference in viscometrics between a Synfluid PAO and a pour point depressed mineral oil. Synfluid PAOs also have a very high degree of saturation, which in lubricants provides oxidative stability. As pressure increases, so too does the viscosity of the lubricant. Air is usually a really poor lubricant, so your frustration is understandable! PAO fluids are classified as a Group IV base oil and are made by a two-step reaction process using linear alpha-olefins like 1-decene. You see, PAOs are carefully designed, not refined. This same technology can also be beneficial for biobased gear lubricants, chain and cable lubricants/greases, and other applications for equipment used in sensitive environmental areas. Polyalphaolefins (PAO)-60 to 125 C Stable, lubricious fluids compatible with most plastics and elastomers. Fluid distribution panels are also discussed. Polyalphaolefins (PAO)-60 to 125 C Stable, lubricious fluids compatible with most plastics and elastomers. So, whether used for gear or engine oils, PAOs provide more consistent properties and a level of purity not available from other base oil groups. With Synfluid PAO 4 cSt having a 73C ppt and 40C viscosity of 2,380 cSt, a PPD is not necessary. More importantly, however, was product performance. JFIF Adobe d ##''$ %'% $('++++'()02520)7;;;;7;;;;;;;;;;;;;;;
""2(! The combination of air and oil can often lead to foaming issues. Chemical Compatibility Guide Adobe PDF Library 10.0.1 0000027693 00000 n
polyalphaolefin compatibility chart. You can see a medical doctor for your burn, but Dr. Ken Hope can help with your base oil and formulation challenges. A drop-in replacement for petroleum, it's used in countless applications in many industries. 91 0 obj For instance, a 100 percent aminic antioxidant package will yield the best performance in the Rbot test for PAO. One example is the advantage PAO has over mineral oil in the area of high-temperature stability. Furthermore, PAOs are H-1 approved for incidental food contact and have good organoleptic properties, which broaden the range of end-use applications for metals. endstream
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A polyolefin is a type of polymer with the general formula (CH 2 CHR) n where R is an alkyl group. Challenges like these truly reveal the performance advantages of Synfluid PAOs. There are multiple considerations when determining the best synthetic lubricant for a particular application, but knowledge of the general properties of the synthetic lubricant types being considered is the starting point. The plot below shows a comparison of the air release times exhibited by ISO VG 320 blends composed of our Synfluid mPAOs, and traditional HV PAOs with PAO 8 cSt. Naval Research Laboratory (USNRL) was begun to develop hydraulic fluids that would be more fire-resistant than the ones used at the time based on mineral oil.
One application in which they have not worked well is in high-temperature (high-pressure) reciprocating air compressors where valve deposits have been an issue. 2 shows the flow chart for producing Cu nanolubricants. They're found in everyday food and available as supplements. III F challenge formulators, and their suppliers, to step up performance for the next generation of engine oils. 0000001332 00000 n
The properties mentioned above are in addition to the normally excellent performance you have come to recognize with PAO. These oligomers are distilled and hydrogenated to yield specific molecular weight ranges that meet the viscosity grades that are desired. We have measured a 25 percent improvement in oxidation induction times simply by decreasing the test temperature by 10 degrees. xmp.iid:00801174072068118083E936383AAE83 0000139372 00000 n
Aluminum is compatible with fluids such as polyalphaolefin (PAO), oil, ethylene glycol and water solutions (EGW), as well as Fluorinert, an electrically insulating inert perfluorocarbon fluid manufactured by 3M and used in many electronics cooling applications. Furthermore, the advantages of exceeding the minimum requirements for driveline fluids will enhance the benefits of the finished lubricant. Flash Point (F) SpectraSyn Plus 3.6. Softening, loss of strength, or swelling may occur. We offer a wide range of solutions essential to your products. However, Group III base stocks are derived from multiple feedstock choices and processing technologies, which create variability in the properties. Its estimated that over 100 million gallons of fluids leak from hydraulic machinery and other lubricant equipment in North America each year! MOLYKOTE. However, VI doesnt tell the whole story it only reflects the viscosity/temperature relationship between 40C and 100C. The viscosity at an extreme pressure (hp) changes exponentially with pressure (P) as described in the following formula: a is the pressure coefficient for a base oil. Furthermore, these new formulations allow a range of ISO viscosity grades. For other applications, PAOs safe and non-toxic nature allows it to be used where incidental food contact certification or kosher approval is necessary. Synfluid PAO improves finished lubricant performance when formulated into biodegradable and biobased lubricants in low-temperature viscometrics and oxidative stability. We offer a wide range of solutions essential to your products. Polyalphaolefin is by far the most common major synthetic base oil used in industrial and automotive lubricants. Defense Daily subscriber and registered users, please log in here to access the content. From then on, the company introduced 1-dodecene-based PAOs in 1995, which have grown steadily in popularity. Our sustainability strategy encompasses the concerns and issues identified by our stakeholders and we are committed to addressing these issues. Thats a hot topic! Because PAOs have a diverse, highly branched isoparaffin structure, they provide excellent low-temperature viscometrics and very low pour points (ppt) without adding PPDs. 176 0 obj concentration from 0.5 percent to 1 percent. Ethylene is produced by cracking either crude oil or natural gas. Since there are no other discernable compounds, Synfluid PAOs are more readily biodegradable and can be used for some food applications. Chemical Compatibility Guide There are emerging markets that demand the improved VI and volatility that only the C12-based PAOs can deliver. 0000000995 00000 n
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Some properties such as Viscosity Index (VI) or C viscosity can approach those of PAOs. 2023 DuPont. 2014-03-26T09:12:59.004-05:00 Compatibility testing includes heating and holding grease for a specified time at assumed operating temperature for mixtures of 10:90, 50:50 and 90:10. I love to talk about food, and I love to talk about Synfluid PAO! polyalphaolefin compatibility chart Posted by . General properties of low- and high-viscosity conventional PAO, and metallocene-catalyzed mPAO basestocks, are shown in Table 4. cally stable, have good compatibility with mineral oils and can be combined with other more polar synthetic basestocks (e.g. general guideline for pump material selection If pour point is not a critical property in your application, then blending a PAO 5 and PAO 7 might give you that clear advantage that you are looking for. 0000000549 00000 n
Specific tests such as the Volkswagen T-4, TDI and Peugeot TU-5 have increased the demand for higher-quality base oils. Polyalphaolefin is by far the most common major synthetic base oil used in industrial and automotive lubricants. Since PAO fluids are synthetic hydrocarbons, they are compatible with and often combined with mineral-based oils. Galvanized steel is susceptible to attack by some chemicals which may cause . The differences in flash, fire, volatility and viscosity highlight the flexibility benefits of using a Synfluid PAO. Low-temperature fluidity and high-temperature thermal and oxidative stability are key factors for choosing a PAO. Ethylene is produced by cracking either crude oil or natural gas. Polyolefin. SYNTHETIC OIL COMPATIBILITY WITH SEAL MATERIAL SEAL MATERIAL PAO ESTER POLYGLYCOL NEOPRENE OK NR NR VITON OK OK OK BUNA-N Less than 30% acrylonitrile OK NR NR 30-36% acrylonitrile OK OK OK Greater than 36% acrylonitrile OK OK OK CELCON OK OK OK TEFLON OK OK OK SILICONE OK OK OK NYLON . Due to this incompatibility with many but not all PAG lubricants, system change-outs from mineral oil to PAG-based lubricants may be costlier and take additional time. PAOs help to balance the protection and energy conservation requirements in equipment because they are more Newtonian than mineral oils. According to analysis conducted by Kline & Co., more than 78% of all lubricant requirements in the world annually are met with the use of mineral oil-based fluids. Additives will increase the overall viscosities; however, PAO base oil leaves plenty of room for meeting specifications. Engine oil tests such as VW T-4 and Seq. The second step is the hydrogenation of the remaining double bonds (unsaturation) in the oligomer and subsequent distillation to separate the unreacted monomer and light-viscosity grade PAO. Due to constraints with the supply of 1-decene, the traditional feedstock for PAOs, producers have experimented with alternative feedstocks to meet demand. The benefit of a lubricant to the end user is an important question, and the behavior of a base oil is only one of many variables affecting the performance of a finished formulation. endobj So yes, PAOs can provide flexibility in your food-grade base oil selection, depending upon your performance requirements. Other base oil properties need to be considered. While typical hydraulic oils are not biodegradable, this new system achieves the ultimate biodegradation rating (ASTM D5864 PW1) and even improves several performance parameters, not previously attainable. The chart below shows that the PAO has a higher specific heat, which means that the PAO is better at absorbing heat. These properties translate into easier distribution of the grease and improved energy efficiency in the equipment. Heavier components adversely affect low-temperature performance and pour point. Its great to have the opportunity to talk about both. Because metalworking processes can generate heat, these properties give you an intrinsic safety margin over the more volatile oils that are typically used. Tiny bubbles these can cause major issues, such as shorter lubricant life, increased fluid compressibility, lower fluid viscosity and cavitation. Meet additional regulations (fire-resistance, environmental acceptability). 56 0 obj<>stream
While pour point is one consideration, a formulator has to take into account the total specification needs. Using Chevron Phillips Chemical Synfluid PAOs, OM Group (OMG) has developed a revolutionary new, lower-temperature, abbreviated process for producing greases. 0000035336 00000 n
The more EO monomer in the basestock, the more water-soluble; the more PO monomer, the more water-insoluble; and the more BO monomer, the more oil-soluble the basestock is. polyalphaolefin-based lubricants. One obvious trend is that low-viscosity oils are beneficial in improving fuel efficiency. The limits on lowering the viscosity grade are tied to the base oil properties. Well be happy to help you solve your lubricant concerns. endobj For other applications, PAOs safe and non-toxic nature allows them to be used where incidental food contact certification or kosher approval is necessary. Were here to help. With the powerful combination of MOLYKOTE. The chart below illustrates the relative effect base oils have on the operating temperatures in a modified four-ball machine. The PAOs . endobj H*T034R0 BC0k ` f-
endobj Additionally, PAOs have high viscosity indices, which lead to less film thickness reduction at elevated temperatures. Low molecular weight compounds will degrade other performance requirements, such as volatility, flash and fire points.
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